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Home > Encyclopedia > DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) structure

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) 

structure
  • CAS No:

    12148-71-9

  • Formula:

    C18H22Ir2O2

  • Chemical Name:

    DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

  • Synonyms:

    DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I);Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I),min.98%;BIS(1,5-CYCLOOCTADIENE) DI-MU-METHOXYDII;[Ir(OMe)(1;5-cod)]2;(1,5-Cyclooctadiene)(methoxy)iridium dimer;Bis[(1,5-cyclooctadiene)(methanolato)iridium];-methoxy)iridium(I) dimer

  • Categories:

    Organic Chemistry  >  Organometallic Compounds

Description

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.


yellow solid

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Basic Attributes

654.81

662.14810

628-411-6

No

yellow

2843909000

Characteristics

154-179 °C (D)

-20°C

Safety Information

3

Xi

26

36/37/38

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 44 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Use and Manufacturing

Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.

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