high quality 3-CYCLOHEXENYLTRICHLOROSILANE 99% transparent liquid KANBEI

4-(Trichlorosilyl)cyclohexene

Cyclohexene,4-(trichlorosilyl)-;Silane,trichloro-3-cyclohexen-1-yl-;4-(Trichlorosilyl)cyclohexene;3-Cyclohexenyltrichlorosilane;1-(Trichlorosilyl)-3-cyclohexene;Trichloro-3-cyclohexen-1-ylsilane

10137-69-6

C6H9Cl3Si

InChIKey=TTYRJPILQGWBOQ-UHFFFAOYSA-N

215.58

215.58

233-377-7

1762

Colorless, fuming liquid

2931900090

Silane Reagent

0

5.93

1.250 g/cm³

<0°C

87-88 °C @ Press: 16 Torr

90°C

1.4905

Reacts violently with water, steam, moist air, alcohols, acetone, light metals with generation of heat and combustible (H2) and corrosive (HCl) gases. on contact with air 3-CYCLOHEXENYLTRICHLOROSILANE gives off HCl gas. REF [Handling Chemicals Safely, 1980 p. 924].

Store in tightly closed containers in a cool, well-ventilated area away from water, steam, and moisture because toxic and corrosive chloride gases, including hydrogen chloride, can be produced. Sources of ignition, such as smoking and open flames, are prohibited where cyclohexenyl trichlorosilane is used, handled, or stored in a manner that could create a potential fire or explosion hazard.

Oral-rat LD50: 2830 mg/kg

Flammable; emits toxic hydrogen chloride gas in water; emits toxic gas in fire

Lower explosive limit: 3.4%; Upper explosive limit: > or = 9.5%

HCl odor

The reaction of organosilanes with halogens and halogen cmpd usually proceeds in good yield through cleavage of the Si--H bond and formation of the silicon-halogen bond. Reaction with fluorine, however, does not proceed satisfactorily because of cleavage of not only the Si--H but also C--Si and C--H bonds. Direct halogenation with chlorination, bromine, and iodine proceeds smoothly, however. /Organosilanes/|Readily hydrolyzed by moisture, with liberation of hydrogen chloride

Reacts violently with water, steam, moist air, alcohols, acetone, light metals with generation of heat and combustible (H2) and corrosive (HCl) gases. on contact with air it gives off HCl gas. REF [Handling Chemicals Safely, 1980 p. 924]. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Chloride gas will be created in 12 minutes. After mixing particular chemicals into water, there may be a delay of 1-10 minutes before gas generation may be observed. For this chemical, a 144 second induction time was observed. Experimental details are in the following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. Brown, H.M. Hartmann, W.A. Freeman, and W.D. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009.

Hydrocarbons, Aliphatic Unsaturated

Water-Reactive

Chlorosilanes, such as CYCLOHEXENYLTRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases. Special Hazards of Combustion Products: Irritating, toxic hydrogen chloride and phosgene may be generated in a fire.

Corrosive