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Lithium hydroxide1310-65-2

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CAS No.:

1310-65-2

Grade:

Pharmaceutical Grade

Content:

99.5%

Port:

上海

Brand:

OORENT

Packaging:

Vial/Bottle/Bag/Carton

Price valid (until):

2026-07-17

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Qingdao Orient Chemical Co.,LTD

Company Type:

Trader

Location:

China

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Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

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Product Description
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Inquiry History

Description

Product Detail

Lithium hydroxide Basic information

Physical Properties Uses Preparation Reaction

Product Name:	Lithium hydroxide
Synonyms:	"Lithium hydroxide, anhydrous/ 99%";Lithium hydroxide ,99% [anhydrous];Lithium Hydroxide Anhydrous [for General Organic Chemistry];LithiuM hydroxide, anhydrous, pure, 98% 500GR;LITHIUM HYDROXIDE 98+ 100 G;LITHIUM HYDROXIDE 98+ 1 KG;Lithium hydroxide powder, reagent grade, >=98%;Lithium hydroxide reagent grade, 98%
CAS:	1310-65-2
MF:	LiOH
MW:	23.95
EINECS:	215-183-4
Product Categories:	iOH;Inorganic chemical, lithium;LEssential Chemicals;Alphabetic;Analytical Standards;metal hydroxide;Inorganics;Reagent Grade;Routine Reagents;K00001
Mol File:	1310-65-2.mol

Lithium hydroxide Chemical Properties

Melting point	470 °C (dec.) (lit.)
Boiling point	925°C
bulk density	550kg/m3
density	1.43
storage temp.	Store below +30°C.
solubility	water: soluble71g/L at 20°C
pka	14[at 20 ℃]
form	Solid
color	White to light yellow
Specific Gravity	2.54
Odor	odorless
PH	12 (50g/l, H2O, 50℃)
Water Solubility	113 g/L (20 ºC)
Sensitive	Air Sensitive & Hygroscopic
Merck	14,5534
Stability:	Stable. Incompatible with moisture. strong acids, carbon dioxide.
Cosmetics Ingredients Functions	HAIR WAVING OR STRAIGHTENING BUFFERING
InChI	1S/Li.H2O/h;1H2/q+1;/p-1
InChIKey	WMFOQBRAJBCJND-UHFFFAOYSA-M
SMILES	[Li+].[OH-]
CAS DataBase Reference	1310-65-2(CAS DataBase Reference)
NIST Chemistry Reference	Lithium hydroxide(1310-65-2)
EPA Substance Registry System	Lithium hydroxide (1310-65-2)

Safety Information

Hazard Codes	C
Risk Statements	52/53-35-20/22-22-34-23
Safety Statements	45-36/37/39-26-22
RIDADR	UN 2679 8/PG II/III (LITHIUM HYDROXIDE SOLUTION)
RIDADR	UN 2680 8/PG II (LITHIUM HYDROXIDE)
WGK Germany	1
RTECS	OJ6307070
TSCA	TSCA listed
HazardClass	8
PackingGroup	II
HS Code	28252010
Storage Class	8A - Combustible corrosive hazardous materials
Hazard Classifications	Acute Tox. 4 Oral Eye Dam. 1 Skin Corr. 1B
Toxicity	LD50 orally in Rabbit: 210 mg/kg

MSDS Information

Provider	Language
ACROS	English
ALFA	English

Lithium hydroxide Usage And Synthesis

Physical Properties	Lithium hydroxide is a white tetragonal crystals; refractive index 1.464; density 1.46 g/cm3; melts at 450°C; decomposes at 924°C; dissolves in water (12.8g/100g at 20°C and 17.5 g/100g at 100°C); slightly soluble in alcohol. Lithium hydroxide monohydrate is white monoclinic crystalline solid; refractive index 1.460; density 1.51 g/cm3; soluble in water, more soluble than the anhydrous salt (22.3g and 26.8g/100g at 10 and 100°C, respectively); slightly soluble in alcohol; insoluble in ether.
Uses	Lithium hydroxide is used as an electrolyte in certain alkaline storage batteries; and in the production of lithium soaps. Other uses of this compound include its catalytic applications in esterification reactions in the production of alkyd resins; in photographic developer solutions; and as a starting material to prepare other lithium salts.
Preparation	Lithium hydroxide is prepared by the reaction of lithium carbonate with calcium hydroxide: Li2CO3 + Ca(OH)2 → 2LiOH + CaCO3 Calcium carbonate is filtered out and the solution is evaporated and crystallized. The product obtained is the monohydrate, LiOH•H2O. The anhydrous compound is obtained by heating the hydrate above 100°C in vacuum or carbon dioxide-free air. The hydroxide also may be prepared by treating lithium oxide with water.
Reaction	Lithium hydroxide is a base. However, it is less basic than sodium or potassium hydroxide. The compound undergoes neutralization reactions with acids: LiOH + HCl → LiCl + H2O Heating the compound above 800°C in vacuum yields lithium oxide: 2LiOH Li2O + H2O Lithium hydroxide readily absorbs carbon dioxide, forming lithium carbonate: 2LiOH + CO2 → Li2CO3 + H2O Passing chlorine through a solution of lithium hydroxide yields lithium hypochlorite: LiOH + Cl2 → LiOCl + HCl Saponification of fatty acids with lithium hydroxide produces lithium soaps. LiOH + CH3(CH2)16COOH → CH3(CH2)16COOLi + H2O (stearic acid) (lithium stearate)
Chemical Properties	lithium hydroxide (LiOH) is a white solid made industrially as the monohydrate (LiOH.H2O) by reacting lime with a lithium ore or with a salt made from the ore. Lithium hydroxide has a closer resemblance to the group 2 hydroxides than to the group 1 hydroxides.
Physical properties	White tetragonal crystals; refractive index 1.464; density 1.46 g/cm³; melts at 450°C; decomposes at 924°C; dissolves in water (12.8g/100g at 20°C and 17.5 g/100g at 100°C); slightly soluble in alcohol. The monohydrate is white monoclinic crystalline solid; refractive index 1.460; density 1.51 g/cm³; soluble in water, more soluble than the anhydrous salt (22.3g and 26.8g/100g at 10 and 100°C, respectively); slightly soluble in alcohol; insoluble in ether.
Uses	The compound is soluble in water. The compound is used in the formulation of lithium soaps used in multipurpose greases; also in the manufacture of various lithium salts; and as an additive to the electrolyte of alkaline storage batteries. LiOH also is an efficient, light-weight absorbent for carbon dioxide.
Uses	Lithium hydroxide is used as a heat transfer medium, as a storage-battery electrolyte and also used for the production of lithium greases. It is also used in ceramics, in some portland cement formulations, in the absoption of carbondioxide from sealed enviornments such as submarines, spacecrafts and breathing apparatus. It is used in esterification reactions, as stabilizer in photographic developments and as a coolant in pressurized water reactors for corrosion control.
Uses	Lithium hydroxide is an alkali metal hydroxide that is used in storage batteries and soaps and as CO2 absorber in spacecrafts.
Definition	A white crystalline solid, LiOH, is soluble in water, slightly soluble in ethanol, and insoluble in ether. It is known as the monohydrate (monoclinic; r.d. 1.51) and in the anhydrous form (tetragonal, r.d. 1.46; m.p. 450°C; decomposes at 924°C). The compound is made by reacting lime with lithium salts or lithium ores. Lithium hydroxide is basic but has a closer resemblance to group 2 hydroxides than to the other group 1 hydroxides (an example of the first member of a periodic group having atypical properties).
General Description	Lithium hydroxide, solution appears as a clear to water-white liquid which may have a pungent odor. Contact may cause severe irritation to skin, eyes, and mucous membranes. It may be toxic by ingestion, inhalation and skin absorption. It is used to make other chemicals.
Air & Water Reactions	Dilution with water may generate enough heat to cause steaming or spattering.
Reactivity Profile	LITHIUM HYDROXIDE SOLUTION neutralizes acids exothermically to form salts plus water. Reacts with certain metals (such as aluminum and zinc) to form oxides or hydroxides of the metal and generate gaseous hydrogen. May initiate polymerization reactions in polymerizable organic compounds, especially epoxides. May generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, various metals, peroxides, and hydroperoxides. May serve as a catalyst. Reacts when heated above about 84°C with aqueous solutions of reducing sugars other than sucrose, to evolve toxic levels of carbon monoxide [Bretherick, 5th Ed., 1995].
Health Hazard	TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard	Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
reaction suitability	core: lithium
Safety Profile	Poison by ingestion and subcutaneous routes. Mtldly toxic by inhalation. A corrosive. When heated to decomposition it emits toxic fumes of Li.
Purification Methods	It crystallises from hot water (3mL/g) as the monohydrate. It is dehydrated at 150o in a stream of CO2-free air. It sublimes at 220o with partial decomposition [Cohen Inorg Synth V 3 1957, Bravo Inorg Synth VII 1 1963].

Lithium hydroxide Preparation Products And Raw materials

Raw materials

Calcium hydroxide-->Lithium carbonate

Preparation Products

Lithium chloride-->1-Boc-3-hydroxymethyl-piperazine-->5-METHYLISOXAZOLE-3-CARBONYL CHLORIDE-->4-[4-(Aminomethyl)pyridin-2-yl]piperazine, N1-BOC protected-->3-(2-FURYL)PROPANOIC ACID-->2,5-Dihydroxyterephthalic acid-->6-BROMO-1-BENZOFURAN-2-CARBOXYLIC ACID-->Lithium bromide-->Molybdenum disulfide lithium-based grease-->lithium base grease-->5-BROMO-1-BENZOFURAN-2-CARBOXYLIC ACID-->5-Bromoindole-2-carboxylic acid-->Lithium nitrate-->5-Chloroindole-2-carboxylic acid-->1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE-->Lithium sulfate-->LITHIUM METASILICATE-->Lithium peroxide-->Lithium acetate dihydrate-->L-LACTIC ACID LITHIUM SALT-->LITHIUM LACTATE-->Lithium acetate-->Lithium chromate

Shop 3-Chloro-1-propene107-05-1-Detailed Image 2

Basic Info

Product Name:

Lithium hydroxide

Other Name:

=98%;Lithium hydroxide reagent grade, 98%">"Lithium hydroxide, anhydrous/ 99%";Lithium hydroxide ,99% [anhydrous];Lithium Hydroxide Anhydrous [for General Organic Chemistry];LithiuM hydroxide, anhydrous, pure, 98% 500GR;LITHIUM HYDROXIDE 98+ 100 G;LITHIUM HYDROXIDE 98+ 1 KG;Lithium hydroxide powder, reagent grade, >=98%;Lithium hydroxide reagent grade, 98%

CAS No.:

1310-65-2

Molecular Formula:

LiOH

InChIKeys:

WMFOQBRAJBCJND-UHFFFAOYSA-M

Molecular Weight:

23.95

Exact Mass:

24.01870

EC Number:

215-183-4

TSCA:

TSCA listed

Color/Form:

White to light yellow

HScode:

28252010

Categories:

Bulk Drug Intermediates

Characteristics

PSA:

23.06000

Physical Properties:

White tetragonal crystals; refractive index 1.464; density 1.46 g/cm3; melts at 450°C; decomposes at 924°C; dissolves in water (12.8g/100g at 20°C and 17.5 g/100g at 100°C); slightly soluble in alcohol. The monohydrate is white monoclinic crystalline solid; refractive index 1.460; density 1.51 g/cm3; soluble in water, more soluble than the anhydrous salt (22.3g and 26.8g/100g at 10 and 100°C, respectively); slightly soluble in alcohol; insoluble in ether.

XLogP3:

-0.17680

Appearance:

White crystal or pill

Density:

1.43

Melting Point:

470 °C (dec.) (lit.)

Boiling Point:

925°C

Water Solubility:

113 g/L (20 ºC)

Storage Conditions:

Storage Room low temperature ventilation drying ,Separate storage with acids

Vapor Pressure:

Vapour pressure, Pa at 20°C: (negligible)

Toxicity:

LD50 orally in Rabbit: 210 mg/kg

Odor:

odorless

PH:

12 (50g/l, H2O, 50℃)

PKA:

14[at 20 ℃]

Air and Water Reactions:

Dilution with water may generate enough heat to cause steaming or spattering.

Reactivity Profile:

LITHIUM HYDROXIDE SOLUTION neutralizes acids exothermically to form salts plus water. Reacts with certain metals (such as aluminum and zinc) to form oxides or hydroxides of the metal and generate gaseous hydrogen. May initiate polymerization reactions in polymerizable organic compounds, especially epoxides. May generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, various metals, peroxides, and hydroperoxides. May serve as a catalyst. Reacts when heated above about 84°C with aqueous solutions of reducing sugars other than sucrose, to evolve toxic levels of carbon monoxide [Bretherick, 5th Ed., 1995].

Critical Temperature & Pressure:

Store below +30°C.

See More Lithium hydroxide Properties 

Hazard Identification

Classification of the substance or mixture

Acute toxicity - Category 4, Oral

Skin corrosion, Sub-category 1B

Serious eye damage, Category 1

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H302 Harmful if swallowed H314 Causes severe skin burns and eye damage
Prevention	P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
Response	P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P316 Get emergency medical help immediately. P321 Specific treatment (see ... on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P317 Get medical help.
Storage	P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Separated from food and feedstuffs, strong oxidants and strong acids. Store only in original container. Dry. Well closed. Store in an area without drain or sewer access.

See More Lithium hydroxide Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

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We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals，food additives, and other fine chemical products.
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Website: orientchem.cc
Email: scarlett@orientchem.cc
WhatsApp: +86 17753254221

Inquiry History

3 Inquiries

Country	Product	Purchase Quantity	Date Posted
Malaysia	Lithium Hydroxide	20.00 KG	Mar 4, 2024
India	Lithium Hydroxide anhydrous	1.00 20' Fcl	Oct 12, 2023
India	Lithium Hydroxide	500 KG	Jun 28, 2023

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