Aloperine
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Aloperine
structure -
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CAS No:
56293-29-9
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Formula:
C15H24N2
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Chemical Name:
Aloperine
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Synonyms:
6,13-Methano-2H-dipyrido[1,2-a:3′,2′-e]azocine,1,3,4,6,6a,7,8,9,10,12,13,13a-dodecahydro-,(6R,6aR,13R,13aS)-;Aloperine;Ormosanine,16,17-didehydro-9-de-2-piperidinyl-,(7α,9α)-;6,13-Methano-2H-dipyrido[1,2-a:3′,2′-e]azocine,ormosanine deriv.;(6R,6aR,13R,13aS)-1,3,4,6,6a,7,8,9,10,12,13,13a-Dodecahydro-6,13-methano-2H-dipyrido[1,2-a:3′,2′-e]azocine;6,13-Methano-2H-dipyrido[1,2-a:3′,2′-e]azocine,1,3,4,6,6a,7,8,9,10,12,13,13a-dodecahydro-,[6R-(6α,6aβ,13α,13aα)]-;1354-23-0
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CAS No:
Description
Aloperine is an alkaloid in sophora plants such as Sophora alopecuroides L, which has shown anti-cancer, anti-inflammatory and anti-virus properties[1]. Aloperine is widely used to treat patients with allergic contact dermatitis eczema and other skin inflammation in China[2]. Aloperine induces apoptosis and autophagy in HL-60 cells[1].
Characteristics
15.27000
2.43570
yellow crystalline powder
1.1±0.1 g/cm3
73-75 °C
367.7°C at 760 mmHg
155.8±17.5 °C
1.583
Safety Information
NONH for all modes of transport
22
RM2979500
Xn
H302
|Warning|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P264, P270, P301+P312, P330, and P501|Aggregated GHS information provided by 38 companies from 1 notifications to the ECHA C&L Inventory.
Aloperine Use and Manufacturing
General procedure: A solution of 1.1 mM amine in methanol (2 mL) was added under stirring to a solution of 1 mM lactone (I) in methanol (5 mL) and allowed to stand at room temperature; the degree of conversion of initial lactone was monitored by TLC. If the product did not precipitate from the reaction mixture, the solvent was evaporated in vacuo after the termination of the reaction, and the residue was recrystallized from the appropriate solvent (usually a mixture of benzene with hexane).The following compounds were obtained by this method.General procedure: To a stirred solution of General procedure: To a stirred solution of General procedure: To a stirred solution of General procedure: To a stirred solution of
Computed Properties
Molecular Weight:232.36
XLogP3:1.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Exact Mass:232.193948774
Monoisotopic Mass:232.193948774
Topological Polar Surface Area:15.3
Heavy Atom Count:17
Complexity:336
Defined Atom Stereocenter Count:4
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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