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2-Dimethylamino-5,6-dimethyl-4-hydroxypyrimidine

2-Dimethylamino-5,6-dimethyl-4-hydroxypyrimidine structure

2-Dimethylamino-5,6-dimethyl-4-hydroxypyrimidine 

structure
  • CAS No:

    40778-16-3

  • Formula:

    C8H13N3O

  • Chemical Name:

    2-Dimethylamino-5,6-dimethyl-4-hydroxypyrimidine

  • Synonyms:

    4(3H)-Pyrimidinone,2-(dimethylamino)-5,6-dimethyl-;4(1H)-Pyrimidinone,2-(dimethylamino)-5,6-dimethyl-;2-(Dimethylamino)-5,6-dimethyl-4(3H)-pyrimidinone;R 31805;2-Dimethylamino-5,6-dimethyl-4-hydroxypyrimidine;2-(Dimethylamino)-5,6-dimethyl-1H-pyrimidin-4-one;2-Dimethylamino-4-hydroxy-5,6-dimethylpyrimidine;2-(Dimethylamino)-5,6-dimethylpyrimidin-4-ol;2-(Dimethylamino)-5,6-dimethyl-3,4-dihydropyrimidin-4-one;42285-51-8

  • Categories:

    Agrochemicals  >  Pesticide Intermediates

2-Dimethylamino-5,6-dimethyl-4-hydroxypyrimidine Basic Attributes

167.20832

167.21

255-074-9

2933599090

Characteristics

44.7

0.45270

1.13g/cm3

243.1ºC at 760mmHg

100.8ºC

1.553

Safety Information

P264, P270, P280, P301+P312, P305+P351+P338, P330, P337+P313, P501

H302

2-Dimethylamino-5,6-dimethyl-4-hydroxypyrimidine Use and Manufacturing

Methods of Manufacturing

2-Dimethylamino-4-hydroxy-5, 6-dimethylpyrimidine is prepared by reacting N, N-dimethylguanidine sulfate with ethyl α-methylacetoacetate. Add 4.6g of acid binding agent, alcohol and 14g of N, N-dimethylguanidine sulfate into a 250mL three-necked flask equipped with a stirrer and a water separator, stir and react for 2h, add 21.2g of ethyl α-methylacetoacetate and solvent, Slowly increase the temperature under stirring until the reaction temperature reaches about 140°C, and keep the reaction for 2 hours. The solvent is recovered under reduced pressure. The solid is dissolved in chloroform and adjusted to pH=7. The chloroform layer is concentrated to dryness. The product is 15.7g, the content is 92.69%, and the yield is 93.43%.

Uses

2-Dimethylamino-4-hydroxy-5,6-dimethylpyrimidine is an intermediate in the synthesis of pesticide anti-aphicarb.

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