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2-Bromotoluene CAS:95-46-5

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CAS No.:

95-46-5

Grade:

Industrail Grade

Content:

99%

Port:

SHANGHAI

Brand:

Orient

Packaging:

25L, 200L, 1000L, customized

Price valid (until):

2025-12-26

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Qingdao Orient Chemical Co.,LTD

Company Type:

Trader

Location:

China

Qualification:

Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

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Product Description
Seller Information

Description

2-Bromotoluene Basic information

Product Name:	2-Bromotoluene
Synonyms:	1-Brom-2-methylbenzol;1-bromo-2-methyl-benzen;1-Methyl-2-bromobenzene;1-BROMO-2-METHYLBENZENE;a13-26648;Benzene,1-bromo-2-methyl-;o-bromo-toluen;o-Methylbromobenzene
CAS:	95-46-5
MF:	C7H7Br
MW:	171.03
EINECS:	202-421-7
Product Categories:	alkyl bromide;Building Blocks;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Intermediates;Organics;Halogen toluene;Miscellaneous;Bromine Compounds;Aryl;C7;Halogenated Hydrocarbons
Mol File:	95-46-5.mol

2-Bromotoluene Chemical Properties

Melting point	-27 °C (lit.)
Boiling point	58-60 °C/10 mmHg (lit.)
density	1.422 g/mL at 25 °C (lit.)
refractive index	n20/D 1.555(lit.)
Fp	174 °F
storage temp.	2-8°C
form	Liquid
color	Clear colorless to light yellow
Specific Gravity	1.422
Water Solubility	<0.1 g/100 mL at 15 ºC
Merck	14,1439
BRN	1904176
Dielectric constant	4.2800000000000002
Stability:	Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference	95-46-5(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-bromo-2-methyl-(95-46-5)
EPA Substance Registry System	o-Bromotoluene (95-46-5)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	22-36/37/38
Safety Statements	36/37/39-37/39-26
WGK Germany	3
RTECS	XS7965500
Hazard Note	Harmful/Irritant
TSCA	Yes
PackingGroup	III
HS Code	29036990
Hazardous Substances Data	95-46-5(Hazardous Substances Data)

2-Bromotoluene Usage And Synthesis

Chemical Properties	liquid
Uses	2-Bromotoluene was used in the synthesis of (±)-isocomene. Suzuki coupling of 2-bromotoluene with phenylboronic acid using palladium nanoparticles supported on alumina-based oxides as catalyst has been reported. 2-Bromotoluene is used in manufacturing pharmaceuticals (especially for nonsteroidal antiinflammatory drugs; Meclofenamic acid, Mefenamic acid) and other organic compounds
General Description	Clear colorless to pale beige liquid.
Air & Water Reactions	Insoluble in water.
Reactivity Profile	2-Bromotoluene reacts with strong oxidizing agents.
Fire Hazard	2-Bromotoluene is combustible.
Purification Methods	Fractionally distil it through an efficient column. It can be separated from its isomers by gas chromatography on a column of “Sil-o-cel” firebrick (30-40mesh, 80 parts) coated with 5% (20 parts) of ICI E301 con rubber with N2 carrier gas at 170o/atm and 100mL/minute and using a conductivity cell detector. [Cowley et al. J Chem Soc 1801 1959, Beilstein 5 H 304, 5 I 153, 5 II 234 5 III 704, 5 IV 825.]

2-Bromotoluene Preparation Products And Raw materials

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Shop Trimellitic Anhydride C9H4O5 552-30-7-Detailed Image 11

Shop Trimellitic Anhydride C9H4O5 552-30-7-Detailed Image 12

—— Q&A ——

Q1:Do you provide sample?

A: Yes, we can provide free sample, you only need pay the shipping cost.

Q2: What is the lead time?

A: For stock goods, it usually take about 5-7 days by air, 15-30 days by sea,For customized products, the delivery time needs to be confirmed based on the actual situation.

Q3: How can I buy? What is the payment method?

A: You can contract us through Email or you can browse our website:orientchem.cc, we have bank transfer,

Q4:What if there are quality issues？

A：We attach great importance to after-sales service of our products. If there are any quality issues, please contact us within 30 days of receiving the goods and we will handle returns and exchanges for you.

Certificates

Basic Info

Product Name:

2-Bromotoluene

Other Name:

Benzene,1-bromo-2-methyl-;Toluene,o-bromo-;1-Bromo-2-methylbenzene;o-Bromotoluene;o-Tolyl bromide;2-Bromotoluene;2-Methylbromobenzene;2-Tolyl bromide;o-Methylphenyl bromide;o-Bromomethylbenzene;o-Methylbromobenzene;2-Bromo-1-methylbenzene;2-Methylphenyl bromide;NSC 6532;2-Methyl-1-bromobenzene

CAS No.:

95-46-5

Molecular Formula:

C7H7Br

InChIKeys:

InChIKey=QSSXJPIWXQTSIX-UHFFFAOYSA-N

Molecular Weight:

171.03

Exact Mass:

171.03

BRN:

1904176

EC Number:

202-421-7

UNII:

TBG2F2VA19

NSC Number:

6532

UN Number:

1760

DSSTox ID:

DTXSID2024660

Color/Form:

COLORLESS LIQ

HScode:

29036990

Categories:

Bulk Drug Intermediates

Characteristics

PSA:

XLogP3:

3.50

Appearance:

Clear colorless to light yellow Liquid

Density:

1.432 g/cm³ @ Temp: 20 °C

Melting Point:

-27.8 °C

Boiling Point:

181.7 °C

Flash Point:

174 °F

Refractive Index:

1.549

Water Solubility:

H2O: <0.1 g/100 mL at 15 ºC;Very soluble in ethanol, ether, and benzene

Storage Conditions:

2-8°C

Vapor Pressure:

1.00 mm Hg @ 25 deg C /Calculated from experimentally-derived coefficients/

Vapor Density:

5.9 (Air= 1)

Toxicity:

Oral-Mouse LD50: 1864 mg/kg; Abdominal cavity-mouse LD50: 1358 mg/kg

Flammability characteristics:

Open flame is flammable; high heat emits bromide gas

Air and Water Reactions:

Insoluble in water.

Reactive Group:

Aryl Halides

Reactivity Profile:

O-BROMOTOLUENE reacts with strong oxidizing agents. (NTP, 1992)

Heat of Vaporization:

11,365.0 gcal/gmole

See More 2-Bromotoluene Properties 

Hazard Identification

Classification of the substance or mixture

Acute toxicity - Category 4, Oral

Skin irritation, Category 2

Eye irritation, Category 2

Specific target organ toxicity â single exposure, Category 3

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Warning
Hazard statement(s)	H302 Harmful if swallowed H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation
Prevention	P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area.
Response	P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P317 If skin irritation occurs: Get medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P319 Get medical help if you feel unwell.
Storage	P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

See More 2-Bromotoluene Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

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We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals，food additives, and other fine chemical products.
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Website: orientchem.cc
Email: scarlett@orientchem.cc
WhatsApp: +86 17753254221
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Raw materials	Copper-->o-Toluidine-->Benzenediazonium, 2-methyl-, tetrafluoroborate(1-)-->2-Bromo-6-methylbenzoic acid-->2,3-Dibromotoluene-->Methyl trifluoromethanesulfonate-->Methyl diiodide-->2,2-dimethylpropane-1,3-diyl [2-bromophenyl] boronate-->O-TOLYLHYDRAZINE HYDROCHLORIDE-->2-Iodotoluene-->1-Bromo-2-iodobenzene-->2-Bromobenzyl alcohol
Preparation Products	L-Leucine-->Tri(o-tolyl)phosphine-->2-Bromobenzoic acid-->BRETYLIUM TOSYLATE-->2-Bromobenzyl bromide-->Methyl 2-bromobenzoate-->o-Tolunitrile-->3,3'-Dimethylbiphe

2-Bromotoluene CAS:95-46-5

Product Description

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